Numerical simulation of dynamic electrochemical impedance spectroscopy using a linearization technique

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{
  "created": "2025-03-26T08:53:12.043214+00:00", 
  "metadata": {
    "license_addendum": null, 
    "keywords": [
      "Finite element method", 
      "Dynamic electrochemical impedance spectroscopy", 
      "Electrochemical system", 
      "Linearization"
    ], 
    "is_last": true, 
    "title": "Numerical simulation of dynamic electrochemical impedance spectroscopy using a linearization technique", 
    "conceptrecid": "2608", 
    "edited_by": 576, 
    "contributors": [
      {
        "email": "potdocci@uni-bremen.de", 
        "familyname": "Pot d'or", 
        "affiliations": [
          "Energiespeicher- und Energiewandlersysteme, Universit\u00e4t Bremen, Bibliothekstra\u00dfe 1, 28359 Bremen, Germany"
        ], 
        "givennames": "C\u00e9cile"
      }, 
      {
        "familyname": "Chukwu", 
        "affiliations": [
          "Energiespeicher- und Energiewandlersysteme, Universit\u00e4t Bremen, Bibliothekstra\u00dfe 1, 28359 Bremen, Germany"
        ], 
        "givennames": "Richard"
      }, 
      {
        "familyname": "Brogioli", 
        "affiliations": [
          "Energiespeicher- und Energiewandlersysteme, Universit\u00e4t Bremen, Bibliothekstra\u00dfe 1, 28359 Bremen, Germany"
        ], 
        "givennames": "Doriano"
      }, 
      {
        "email": "lamantia@uni-bremen.de", 
        "familyname": "La Mantia", 
        "affiliations": [
          "Energiespeicher- und Energiewandlersysteme, Universit\u00e4t Bremen, Bibliothekstra\u00dfe 1, 28359 Bremen, Germany"
        ], 
        "givennames": "Fabio"
      }
    ], 
    "references": [
      {
        "citation": "C. Pot d'or, R. Chukwu, D. Brogioli, F. La Mantia, submitted to ChemElectroChem on 28 March 2025", 
        "comment": "Paper in which the linearization technique is discussed", 
        "type": "Journal reference"
      }, 
      {
        "citation": "F. Taherkhani, D. Brogioli, F. La Mantia, Electroanalysis 35, e202200257 (2023)", 
        "doi": "10.1002/elan.202200257", 
        "comment": "Paper where the semi-analytical model is described", 
        "type": "Journal reference", 
        "url": "https://analyticalsciencejournals.onlinelibrary.wiley.com/doi/full/10.1002/elan.202200257"
      }
    ], 
    "license": "Creative Commons Attribution 4.0 International", 
    "_oai": {
      "id": "oai:materialscloud.org:2609"
    }, 
    "status": "published", 
    "doi": "10.24435/materialscloud:fn-1y", 
    "owner": 1717, 
    "id": "2609", 
    "publication_date": "Apr 08, 2025, 13:34:26", 
    "description": "We present a simulation of dynamic electrochemical impedance spectroscopy using numerical methods based on the finite element solution of differential equations. While the study of electrochemical systems during operation is of great interest, one is always confronted with challenges due to non-linearities when exciting the system with both a cyclic voltammetry and a multi-sine. We therefore propose a two-component-model, which first solves for the cyclic voltammetry and then calculates the effect of the multi-sine by means of linearization around the cyclic voltammetry of all the variables. We provide two models: (i) the dynamic transfer function model of DEIS during a redox reaction and  (ii) a stationary version of model (i). Both models are based on an existing semi-analytical model described in reference #2.", 
    "mcid": "2025.56", 
    "version": 1, 
    "_files": [
      {
        "size": 13335190, 
        "description": "COMSOL file with the dynamic transfer function model", 
        "key": "M1_dynamic_transfer_function_model.mph", 
        "checksum": "md5:af8bd1819502e52d7ccf5684bd826c71"
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      {
        "size": 504310, 
        "description": "COMSOL model as Java file with the dynamic transfer function model", 
        "key": "M1_dynamic_transfer_function_model.java", 
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        "description": "COMSOL file with the stationary transfer function model", 
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  }, 
  "updated": "2025-04-08T11:34:26.649549+00:00", 
  "id": "2609", 
  "revision": 5
}