From operando investigations to implementation of Ni-MOF-74 oxygen evolution electrocatalysts

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{
  "created": "2024-09-30T09:28:47.856976+00:00", 
  "revision": 3, 
  "updated": "2025-03-12T13:21:53.306131+00:00", 
  "id": "2366", 
  "metadata": {
    "is_last": true, 
    "doi": "10.24435/materialscloud:m1-4v", 
    "license": "Creative Commons Attribution 4.0 International", 
    "license_addendum": null, 
    "references": [
      {
        "citation": "J. Linke, T. Rohrbach, A. H. Clark, M. Andrzejewski, N. P. M. Casati, F. L. Buchauer, M. R. Kraglund, C. Chatzichristodoulou, E. Meade, M. Ranocchiari, T. J. Schmidt, E. Fabbri, Advanced Energy Materials (submitted).", 
        "type": "Journal reference", 
        "comment": ""
      }
    ], 
    "description": "Metal-organic frameworks (MOFs) as electrocatalysts for the alkaline oxygen evolution reaction (OER) show promising catalytic activity by offering great variability and high surface areas, enabling performance optimization and mechanistic studies. However, their stability during reaction and the structure-performance relationship defining the origin of the high OER activity, are still vigorously debated. Herein, we leverage operando X-ray absorption spectroscopy and operando X-ray diffraction to unveil the structural and electronic transformations of Ni-MOF-74 during OER. We identify the irreversible destruction of the MOF-74 crystal into a highly OER active, amorphous NiOOH-metal organic compound. Based on these findings, we propose an amorphous Ni metal organic compound (Ni-MOC*) for achieving high current densities both in a three-electrode cell (14 A gNi-1 at 1.5 VRHE) and in an anion exchange membrane water electrolyzer (AEM-WE) with a stable AEM-WE performance exceeding 100 h at 500 mA cm-2.", 
    "mcid": "2025.38", 
    "status": "published", 
    "contributors": [
      {
        "affiliations": [
          "Paul Scherrer Institute (PSI) Center for Energy and Environmental Sciences, Villigen, Aargau, Switzerland"
        ], 
        "givennames": "Julia", 
        "familyname": "Linke"
      }, 
      {
        "affiliations": [
          "Paul Scherrer Institute (PSI) Center for Energy and Environmental Sciences, Villigen, Aargau, Switzerland"
        ], 
        "givennames": "Thomas", 
        "familyname": "Rohrbach"
      }, 
      {
        "email": "adam.clark@psi.ch", 
        "affiliations": [
          "Paul Scherrer Institute (PSI) Center for Photon Science, Villigen, Aargau, Switzerland"
        ], 
        "givennames": "Adam Hugh", 
        "familyname": "Clark"
      }, 
      {
        "affiliations": [
          "Paul Scherrer Institute (PSI) Center for Photon Science, Villigen, Aargau, Switzerland"
        ], 
        "givennames": "Michal", 
        "familyname": "Andrzejewski"
      }, 
      {
        "affiliations": [
          "Paul Scherrer Institute (PSI) Center for Photon Science, Villigen, Aargau, Switzerland"
        ], 
        "givennames": "Nicola Pietro Maria", 
        "familyname": "Casati"
      }, 
      {
        "affiliations": [
          "Department of Energy Conversion and Storage, Technical University of Denmark, Kongens Lyngby, Denmark"
        ], 
        "givennames": "Fabian Luca", 
        "familyname": "Buchauer"
      }, 
      {
        "affiliations": [
          "Department of Energy Conversion and Storage, Technical University of Denmark, Kongens Lyngby, Denmark"
        ], 
        "givennames": "Mikkel Ryk\u00e6r", 
        "familyname": "Kraglund"
      }, 
      {
        "affiliations": [
          "Department of Energy Conversion and Storage, Technical University of Denmark, Kongens Lyngby, Denmark"
        ], 
        "givennames": "Christodoulos", 
        "familyname": "Chatzichristodoulou"
      }, 
      {
        "affiliations": [
          "Paul Scherrer Institute (PSI) Center for Energy and Environmental Sciences, Villigen, Aargau, Switzerland"
        ], 
        "givennames": "Eibhlin", 
        "familyname": "Meade"
      }, 
      {
        "affiliations": [
          "Paul Scherrer Institute (PSI) Center for Energy and Environmental Sciences, Villigen, Aargau, Switzerland"
        ], 
        "givennames": "Marco", 
        "familyname": "Ranocchiari"
      }, 
      {
        "affiliations": [
          "Paul Scherrer Institute (PSI) Center for Energy and Environmental Sciences, Villigen, Aargau, Switzerland", 
          "Eidgen\u00f6ssische Technische Hochschule Z\u00fcrich (ETHZ), Institute of Molecular Physical Science, Z\u00fcrich, Switzerland"
        ], 
        "givennames": "Thomas Justus", 
        "familyname": "Schmidt"
      }, 
      {
        "email": "emiliana.fabbri@psi.ch", 
        "affiliations": [
          "Paul Scherrer Institute (PSI) Center for Energy and Environmental Sciences, Villigen, Aargau, Switzerland"
        ], 
        "givennames": "Emiliana", 
        "familyname": "Fabbri"
      }
    ], 
    "edited_by": 576, 
    "_files": [
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        "description": "Raw Data for Figure 1", 
        "key": "Figure1.7z", 
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    ], 
    "owner": 1508, 
    "conceptrecid": "2365", 
    "version": 1, 
    "_oai": {
      "id": "oai:materialscloud.org:2366"
    }, 
    "keywords": [
      "OER", 
      "MARVEL", 
      "electrocatalysis", 
      "Ni-MOF-74", 
      "alkaline/AEM water electrolysis", 
      "operando XAS/XRD"
    ], 
    "id": "2366", 
    "publication_date": "Mar 12, 2025, 14:21:53", 
    "title": "From operando investigations to implementation of Ni-MOF-74 oxygen evolution electrocatalysts"
  }
}